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〈論文・報告〉ポリベンゾイミダゾールを利用した水酸化物イオン伝導性材料の開発
https://doi.org/10.15100/0000021091
https://doi.org/10.15100/00000210911dc5a046-2b42-414c-8a22-a69b5210b81c
名前 / ファイル | ライセンス | アクション |
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AA12013209-20200630-0001.pdf (1.9 MB)
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Item type | ☆紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2020-09-22 | |||||
タイトル | ||||||
言語 | ja | |||||
タイトル | 〈論文・報告〉ポリベンゾイミダゾールを利用した水酸化物イオン伝導性材料の開発 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | 〈PAPERS and REPORTS〉Development of Hydroxide Ion Conducting Materials Utilizing Polybenzimidazole | |||||
著者 |
舟橋, 恵美
× 舟橋, 恵美× 松本, 幸三 |
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言語 | ||||||
言語 | jpn | |||||
キーワード | ||||||
主題 | Fuel cell, Anion exchange, Benzimidazole, Ion conduction, Hydroxide ion | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
ID登録 | ||||||
ID登録 | 10.15100/0000021091 | |||||
ID登録タイプ | JaLC | |||||
著者 所属 | ||||||
近畿大学大学院産業理工学専攻生物環境化学コース | ||||||
著者 所属 | ||||||
近畿大学産業理工学部生物環境化学科; 教授 | ||||||
版 | ||||||
出版タイプ | NA | |||||
出版タイプResource | http://purl.org/coar/version/c_be7fb7dd8ff6fe43 | |||||
出版者 名前 | ||||||
出版者 | 近畿大学産業理工学部 | |||||
書誌情報 |
ja : かやのもり:近畿大学産業理工学部研究報告 en : Reports of Faculty of Humanity-Oriented Science and Engineering, Kindai University 号 31, p. 1-6, 発行日 2020-06-30 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 13495801 | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Two polybenzimidazole-derived cationic polymers were synthesized, and their chemical and physical properties were investigated to develop hydroxide ion conducting materials for anion exchange polymer membrane fuel cells (AEMFC). One was poly(methylbenzoimidazoliumiodide) (PBI-E-3.8MI), which was synthesized by N-methylation of polybenzoimidazole having ether oxygen (PBI-E). The other was polybenzoimidaozole having propytrimethylammonium bromide groups (PBI-DB-1.4TAB), which was synthesized by introduction of propyltrimethylammonium groups on the imidazole nitrogen. PBI-E-3.8MI showed high thermal stability but low alkaline resistance with low anion exchange ability. On the other hand, PBI-DB-1.4TAB exhibited moderate thermal stability but high alkaline resistance with high anion exchange ability. PBI-DB-1.4TAB film also showed good ionic conductivity under alkaline conditions along with a good mechanical strength. These results suggested that PBI-DB-1.4TAB can be a good candidate as hydroxide ion conducting materials for AEMFC. | |||||
言語 | en | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf |