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〈原著論文〉イオン液体を活用した効果的なテトラフェニルポルフィリンの銅(Ⅱ)錯体化
https://kindai.repo.nii.ac.jp/records/20372
https://kindai.repo.nii.ac.jp/records/203723047988a-7352-4727-acc2-bb7a9f48d452
名前 / ファイル | ライセンス | アクション |
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AA12517632-20191000-0083.pdf (701.2 kB)
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Item type | ☆紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2019-11-15 | |||||
タイトル | ||||||
タイトル | 〈原著論文〉イオン液体を活用した効果的なテトラフェニルポルフィリンの銅(Ⅱ)錯体化 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Effective Copper(Ⅱ) Metalation of Tetraphenylporphyrin Utilizing Ionic Liquids | |||||
著者 |
北岡, 賢
× 北岡, 賢× 堀, 哲郎 |
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言語 | ||||||
言語 | jpn | |||||
キーワード | ||||||
主題 | Ionic Liquids, Porphyrin, Green Chemistry, Metalation, Sustainable Chemistry | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
著者(英) | ||||||
en | ||||||
KITAOKA,Satoshi | ||||||
著者(英) | ||||||
en | ||||||
HORI,Tetsuro | ||||||
著者 所属 | ||||||
近畿大学エ学部化学生命工学科; 講師: 近畿大学次世代基盤技術研究所; 講師 | ||||||
著者 所属 | ||||||
近畿大学大学院システムエ学研究科システムエ学専攻; 博士前期課程 | ||||||
著者所属(翻訳) | ||||||
Kindai University | ||||||
著者所属(翻訳) | ||||||
Kindai University | ||||||
版 | ||||||
出版タイプ | NA | |||||
出版タイプResource | http://purl.org/coar/version/c_be7fb7dd8ff6fe43 | |||||
出版者 名前 | ||||||
出版者 | 近畿大学次世代基盤技術研究所 | |||||
書誌情報 |
近畿大学次世代基盤技術研究所報告 en : Annual Report of Fundamental Technology for Next Generation Research Institute, Kindai University 巻 10, p. 83-87, 発行日 2019-10 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 21858802 | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Metalation of porphyrins is usually carried out in a carefully chosen solvent that offers mutual solubility to both the metal salt and free-base porphyrin. However, these methods suffer from certain disadvantages, such as slow reaction rates, low yields, high boiling solvents. Recently, it has become clear that several ionic liquids dissolve both porphyrins and metal salts. Herein, we reported that metalation of TPP utilizing ionic liquids. In [C8mim][Br], Cu(Ⅱ)-TPP complex is obtained 79 % yields. In the presentation, we report detail reaction condition and effective ionic liquids structure for the metalation. | |||||
目次 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Ⅲ.論文集 | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf |