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1,4-ジオキサン水溶液系の過剰モル熱容量
https://kindai.repo.nii.ac.jp/records/9552
https://kindai.repo.nii.ac.jp/records/9552ca2234c4-2e29-4fa0-8228-9eba90427788
名前 / ファイル | ライセンス | アクション |
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AN00064168-20090930-0009.pdf (1.7 MB)
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Item type | ☆紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2010-09-15 | |||||
タイトル | ||||||
タイトル | 1,4-ジオキサン水溶液系の過剰モル熱容量 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Excess Molar Heat Capacities of Aqueous Mixture of 1,4-Dioxane | |||||
著者 |
鈴木, 隆
× 鈴木, 隆× 吉原, 吉紀× 木村, 隆良 |
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言語 | ||||||
言語 | jpn | |||||
キーワード | ||||||
主題 | Excess heat capacity, Solution structure, Hydrogen bond, Hydrophobic hydration | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
著者(英) | ||||||
en | ||||||
SUZUKI, Takashi | ||||||
著者(英) | ||||||
en | ||||||
YOSHIHARA, Yoshiki | ||||||
著者(英) | ||||||
en | ||||||
KIMURA, Takayoshi | ||||||
著者 所属 | ||||||
近畿大学工業高等専門学校総合システム工学科 | ||||||
著者 所属 | ||||||
近畿大学理工学部理学科化学コース | ||||||
著者 所属 | ||||||
近畿大学理工学部理学科化学コース | ||||||
版 | ||||||
出版タイプ | NA | |||||
出版タイプResource | http://purl.org/coar/version/c_be7fb7dd8ff6fe43 | |||||
出版者 名前 | ||||||
出版者 | 近畿大学理工学部 | |||||
書誌情報 |
近畿大学理工学部研究報告 en : Journal of the Faculty of Science and Engineering, Kinki University 号 45, p. 9-14, 発行日 2009-09-01 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 03864928 | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The excess molar heat capacities of (1-x) water + x1,4-dioxane have been measured by using SETARAM BT2.15D conduction type micro calorimeter from 318.15 K to 368.15 K. In all temperature regions, the mixtures showed positive values over the whole composition range. The excess molar heat capacities over the whole composition range increased with increasing temperature. The maximums of excess molar heat capacities increased proportionately with the increasing temperature. The mole fractions at the maximum value of excess molar heat capacities were shifted from x = 0.55 to 0.50 with increasing temperature from 318.15 K to 343.15 K, however the ones were fixed around x = 0.50 above 343.15 K. Several different behaviors for the concentration dependence of partial molar excess heat capacities were observed from 318.15 K to 368.15 K. An interesting behavior of partial molar excess heat capacities at infinite dilution was observed between 333.15 K and 338.15 K. | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf |